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By Userman
#150545 maybe this is a stupid answer, but, since the nature is only important during fights, couldn't you change it as soon as the battlecontroller between player with synchronize poke and wild poke is constructed and when a pokeball is thrown at it instead of when it spawns?
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By Some Body
#150546 This becomes a problem if the player runs/loses, as now you have Nature-bending Pokémon for when other players/wild Pokémon battle them and it is also exploitable to run until you land the 50% chance of Synchronize activating. Also remember that sidemods exist that display Natures before engaging in battle, making the Nature change obvious to other players.